ACTIVITY
Brewing Up Some Halloween Chemistry!
What happens when you combine a carved pumpkin with one of the most popular chemistry demonstrations of all time? A spectacular Halloween eruption of foamy fun!
This pumpkin-themed Elephant Toothpaste activity is the perfect way to add seasonal excitement to your science lessons while exploring chemical reactions, catalysts, and decomposition. Students will love the dramatic results, and you’ll love the meaningful science behind the spectacle.
Because of water’s unique molecular properties, its observable physical properties impact our daily lives in ways we don’t often notice. This activity provides you with visual and quantitative evidence of the phenomena of adhesion, cohesion, and surface tension in water. You will compare these properties of water for deionized water and deionized water with Dawn dish detergent added to make sense of how water’s polar nature determines its physical properties.
How does the addition of a catalyst affect reaction rate?
Hydrogen peroxide at 30% is a very strong oxidizer. It is corrosive to clothing and will cause burns if spilled on the skin. Use appropriate personal protective equipment (PPE), such as gloves, chemical splash goggles, and lab coats or aprons, to avoid contact. Know and follow all federal, state, and local regulations, as well as school district guidelines, for the disposal of laboratory waste.
This activity addresses the following concepts:
Develop a model to illustrate that the release or absorption of energy from a chemical reaction system depends on changes in total bond energy.
Use reaction-time data and a potential energy diagram to construct a model of catalyzed and uncatalyzed reactions.
Develop a model showing that the release or absorption of energy from a chemical reaction system depends on changes in total bond energy.
Changes of energy and matter in a system can be described in terms of flows into, out of, and within that system.
Upon completion of this demonstration, rinse and dry the bottles before putting them away. Keep PPE on in case a bottle contains leftover hydrogen peroxide. Unless otherwise prohibited, carefully roll up the foam and catalyst on the trash bag and discard it in the trash.
| Reaction | Time (s) | Observations |
|---|---|---|
| Uncatalyzed Reaction | Will vary with temperature | May see small bubbles |
| Catalyzed Reaction | Instantaneous–runs for about 2 minutes | Large amounts of foam spew out of the bottle |
What evidence indicates that a reaction took place?
Bubbles were produced.
Why was dishwashing detergent added to the hydrogen peroxide?
The detergent traps the oxygen bubbles, making a foam that allows the bubbles to be more visible and last longer.
Why was the solid potassium iodide added to one of the bottles?
It serves as a catalyst.
Compare the times for the 2 reactions. Using the time data, write a statement explaining what catalysis is.
When a reaction time is relatively slow and needs to be faster, a catalyst can be added. A catalyst reaction has a shorter reaction time because the addition of a catalyst lowers activation energy. See the explanation of the reaction mechanism below.
Hydrogen peroxide (H2O2 ) is stable for at least a year if stored in an airtight opaque container at room temperature. Common in first aid kits, a 3% H2O2 solution can be applied to minor cuts and abrasions. When the solution contacts tissue and blood, it rapidly decomposes into water (H2O) and oxygen gas (O2).
2H2O2( l ) → 2H2O( l ) + O2( g )
The oxygen gas creates a foam that lifts and washes contaminants out of the wound. This rapid decomposition can only happen in the presence of a catalyst. In the human body that catalyst is catalase, a biological catalyst in blood and tissue. Catalase can lower the activation energy from 75 kJ/mol to about 8 kJ/mol. In this demonstration, solid potassium iodide (KI) dissolves in aqueous H2O2 , forming an aqueous iodide ion (I –) and catalyzing the reaction of aqueous H2O2. The steps of the reaction mechanism are as follows:
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